有机气体吸附材料和其吸附性能研究.pdfVIP

摘要 针对低成本有效去除环境中有害苯乙烯气体的需求，本文研究制备了两种功能 化非织造布吸附材料，通过动态吸附实验研究了两种材料对苯乙烯的吸附性能。采 用紫外光(UV)辐照接枝的方法在聚丙烯(PP)非织造布上接枝丙烯酸十二酯，制备了 能够快速吸附苯乙烯气体的功能非织造布，并探究了单体浓度、辐照时间、光敏剂 浓度以及转移引发终止剂浓度对接枝率的影响。用衰减全反射傅立叶红外光谱 (FT-IRATR)、接触角(CA)和电子显微镜(SEM)对接枝前、后非织造布的形貌进行了 表征，重点研究了不同接枝率、不同吸附温度以及不同气体流速对苯乙烯气体吸附 效果的影响。研究发现，当接枝率为132．25％时，苯乙烯气体的吸附透过时间由 PP非织造布的50 min增加到紫外光辐照引发接枝的80 rnin。 采用高能电子束(EB)辐照接枝的方法在聚丙烯(PP)非织造布上接枝苯乙烯，制 得PP—ST-DVB非织造布，然后通过交联反应将PP—ST-DVB制备成超高交联非织造 布。探究了单体浓度和辐照剂量对接枝率的影响。以4，4t．一--氯甲基联苯为交联剂， 通过交联反应将PP—ST-DVB制备成超高交联非织造布，研究了PP．ST-DVB接枝率、 催化剂、反应温度、反应时间以及n(st)：n(CMDP)：n(SnCl4)对超高交联非织造布比 表面积的影响，同时，使用衰减全反射傅立叶红外光谱(FT-IR ATR)和电子显微镜 (SEM)对接枝前、后非织造布的形貌进行了表征，采用BET法对超高交联非织造布 的孔径以及比表面积进行了测定。重点研究了不同比表面积、不同吸附温度以及不 同气体流速对苯乙烯气体吸附效果的影响。 关键词：功能化非织造布；超高交联；吸附；苯乙烯 Abstract In order to removal the harmful styrene from the environment，two functional nonwoven absorbent materials were prepared in this paper．The adsorption property of the two materials for styrene was studied through dynamic adsorption experiments．A new adsorbent was prepared through graft polymerization of lauryl acrylate in the polypropylene(PP) nonwoven fabric initiated by ultraviolet(UV)for styrene adsorption．The factors influencing the grafting degree were discussed，such as the concentration of monomer,inhibitor and photosensitizer，irradiation time．The chemical and morphological changes of the PP nonwoven fabric and grafted nonwoven fabric were characterized by the fourier transform infrared(FT—IR)attenuated total reflectance(ATR)，contact angle(CA)and scanning electron microscopy(SEM)．The factors of influencing on adsorption capacity were discussed，such as the different adsorption temperature，grafting degree and flow rate．Contrasted with the PP nonwoven fabric，when the degree of grafting was similar to 1 32．25％initiated by UV． the breakthrough time increased from 50 min to 80 min． PP-ST-DVB was prepared through graft polymerization of styrene in the polypropylene(PP)nonwoven fabric initiated by high energy electron beam(EB)．The factors influencing