02 - DIFFUSION PRINCIPLES.pptVIP

DIFFUSION MASS TRANSFER PRINCIPLES INTERACTION OF TWO PHASES V PHASE AND L PHASE COMPOSITIONS TERMINAL STREAMS UNITS MASS MOLAL SUBSCRIPTS COMPONENT NOT PHASE r.it/img/fig3.gif EQUILIBRIUM DRIVING FORCES THERMODYNAMICS FIRST AND SECOND LAWS DEGREES OF FREEDOM INTERPHASE MASS TRANSFER RATES UNITS - FLUXES, DIFFUSION RATES, MASS (MOLE)/UNIT AREA/UNIT TIME. RATE EQUATION TRANSFER RATE = DRIVING FORCE/RESISTANCE (2.3.1) ANALOGS FOR MOMENTUM AND HEAT (6.1-2 AND 6.1-2) UNITS (AREA/TIME) FICK’S 1st LAW dz = B.L. DIFFUSION MECHANISMS MOLECULAR GASES LIQUIDS SOLIDS /watch?v=H7QsDs8ZRMI /watch?v=3xx4AUcT-D4 /netlogo/models/run.cgi?SolidDiffusion.639.542 DIFFUSION MECHANISMS CONVECTIVE /news/n0210/31etna/ DIFFUSIVITY ADJUSTABLE PARAMETER UNITS OF AREA/TIME (m2/sec) SIGN CONVENTION IS NEGATIVE FLUX JAz UNITS MASS OR MOLES/AREA/TIME MEASURED DAB FIGURE 6.2-2 MASS TRANSFER COEFFICIENT NA – MASS TRANSFER RELATIVE TO A FIXED POSITION J*Az – MASS TRANSFER RELATIVE TO MASS OR MOLAR AVERAGE VELOCITY OVERALL CONCENTRATION DIFFERENCE GAS DIFFUSION EQUIMOLAR CONSTANT TOTAL PRESSURE EQUAL FLUXES UNICOMPONENT CONSTANT PRESSURE STAGNANT B PARTIAL PRESSURES OR MOLE FRACTIONS MOLECULAR CONVECTION APPLIES TO ALL PHASES COMBINED MECHANISMS TOTAL CONVECTION RESULT SPECIAL CASES DIFFUSION FROM SPHERES ADSORPTION REACTIONS /Sphere/HirezReactionDiffusionSphere02.htm GAS PHASE DAB VALUES MEASURED VALUES (TABLE 6.2-1) STATISTICAL MECHANICS (L-J) YIELDS: GROUP CONTRIBUTIONS YIELDS: GAS PHASE DAB VALUES CRITICAL PROPERTIES: OTHERS IN PERRY’S, SECTION 5 AND REID, PRAUSNITZ POLING, SECTION 11