异相水解水热晶化两步法制备漂浮光催化剂.docVIP

淮北师范大学 2011届学士学位论文 异相水解水热晶化两步法制备漂浮型光催化剂 学院、专业 化学与材料科学、材料化学 研 究 方 向 无机化学 学 生 姓 名 桂玉婷 学 号 20071441064 指导教师姓名 张茂林 指导教师职称 副 教 授 2010年10月 日  目 录 摘要 ……………………………………………………………………………3 Abstract ……………………………………………………………………4 1.引言 ………………………………………………………………………5 2.实验部分 …………………………………………………………………5 2.1仪器与试剂 ………………………………………………………………5 2.2实验方法 …………………………………………………………………6 2.2.1负载型漂浮光催化剂的光催化剂的表征光催化实验和分析方法3.1负载光催化剂的物相组成和TiO2平均晶粒尺寸3.2 TiO2/飘珠的光催化性能4.结论 ………………………………………………………………………10 5.参考文献 …………………………………………………………………10  异相水解水热晶化两步法制备漂浮光催化剂从廉价的粉煤灰中分离出空心微球飘珠为载体，采用一种简单的异相水解水热晶化两步法合成了TiO2/飘珠漂浮光催化剂，该制备方法不需要煅烧过程，不破坏载体的微结构，可以保持催化剂的漂浮性能。通过SEM、XRD、BET表征，并以正癸烷的太阳光催化降解为模型反应，考察了催化剂的光催化活性。结果显示，TiO2均匀地负载在飘珠TiO2／飘珠漂浮光催化剂能有效地利用太阳光催化降解水面漂浮的有机物光催化剂；异相水解；水热晶化；两步法；Preparation of Floating Photocatalyst by Two-Step Method of Heterogeneous Hydrolyzation and Hydrothermal Crystallization Abstract： Through two-step method of heterogeneous hydrolyzation and hydrothermal crystallization, the floating coated photocatalyst, TiO2/floating bead, was prepared by depositing the TiO2 particles onto hollow microsphere floater which was separated from the fly ash for floating carrier material. This preparation method has many advantages, such as without calcination and destruction of the microstructure of the carrier material, and the photocatalyst will show a good floating property. The photocatalyst TiO2/floating bead was characterized by SEM, XRD and BET, and the model reaction of the photocatalytic degradation of decane under the sunlight irradiation was employed to investigate its photocatalytic activity. The results indicated that the anatase TiO2 nanoparticles were uniformly distributed on the floating beads, and the photocatalytic activity of the TiO2/floating bead was excellent for degradation of organic pollutants floated on water. Keyword: photocatalyst; heterogeneous hydrolyzation; hyd