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Exceptionally Flame Retardant Sulfur-Based Multilayer Nanocoating for Polyurethane Prepared from Aqueous Polyelectrolyte Solutions 来自聚电解质水溶液的含硫基多层纳米特殊火焰的阻燃剂聚氨酯制备 Galina Laufer,? Christopher Kirkland,? Alexander B. Morgan,? and Jaime C. Grunlan*,Department of Mechanical Engineering, Texas AM University, College Station, Texas 77843, United StatesEnergy Technology and Materials Division, University of Dayton Research Institute, Dayton, Ohio 45469, United States ABSTRACT:Many current flame retardant (FR) strategies for polymers contain environmentally harmful compounds and/or negatively impact processing and mechanical properties. In an effort to overcome these issues, an effective flame retardant nanocoating comprised of positively charged chitosan (CH) and anionic poly(vinyl sulfonic acid sodium salt) (PVS) was deposited onto flexible polyurethane foam using layer-by-layer (LbL) assembly. This coating system completely stops foam melt dripping upon exposure to the direct flame from a butane torch. Furthermore,10CH-PVS bilayers (30 nm thick) add only 5.5% to the foam’s weight and completely stop flame propagating on the foam due to the fuel dilution effect from non flammable gases (e.g, water, sulfur oxides, and ammonia) released from the coating during degradation. Cone calorimetry reveals that this same coated foam has a 52% reduction in peak heat release rate relative to an uncoated control. This water-based, environmentally benign nanocoating provides an effective postprocess flame retardant treatment for a variety of complex substrates (foam, fabric,etc.). 摘要：目前，很多聚合物的阻燃（FR）策略含有对环境有害的化合物和/或负面影响加工性能和机械性能。为了克服这些问题，在有效的阻燃纳米涂层组成的带正电荷的壳聚糖（CH）和阴离子聚（乙烯基磺酸钠盐）（PVS）沉积到软质聚氨酯泡沫层由层/层（层层）组装。这涂料体系泡沫完全停止后，丁烷火炬。此外，10CH-PVS双层（?30nm厚）泡沫的体重只增加5.5％，至完全停止火焰传播由于非易燃气体燃料稀释效果（例如，水，泡沫在降解过程中从涂层中释放的硫氧化物，氨等）的。锥体量热表明，相对于无涂层的控制涂层泡沫具有热峰值降低52％释放率。将该水基，环保良性纳米涂层提供了一个有效后处理适用于各种复杂的底物（泡沫，织物的阻燃处理，等等）。 The United States’ National Fire Protection Association estimated that upholstery furniture and beddin