SAS-1.docVIP

Hirsch Teil 1. What are chemical sensors? - Definition !!! 2. Selectivity - Definition - Equilibrium based selectivity: free energy, dielectric constant and distance, - Kinetic based selectivity: steady-state regime 3. Recognition Methods - Ion recognition: recognition-electric charge, selectivity-size, transduction-potentiometric, optical methods e.g. PH electrode ---- part 3 - Recognition by affinity interactions: reversible, non-covalent bonds-ionic bonds, hydrogen bonds, van der Waals interaction = result in a molecular assiciation complex; also respect to shape an