第四章持久性有毒有机污染物降解081010题库.ppt

Outline 1. Introduction 2. Classification 3. Distribution 4. Hazards 5. Degradation 6. Conclusion Introduction PTS are a set of chemicals that are toxic, persistent in the environment for long periods of time, and biomagnify as they move up through the food chain. PTS have been linked to adverse effect on human health and animals, such as cancer, damage to the nervous system, reproductive disorders, and disruption of the immune system. They can circulate globally via the atmosphere, oceans, and the other pathways. Introduction: Classification The initial group of PTS includes 12 PTS in three major categories according to the groundbreaking United Nations treaty in Stockholm, Sweden, in may 2001. Classification The insecticides aldrin, chlordane, DDT, dieldrin, endrin, heptachlor, hexachlorobenzene, mirex, and toxaphene Classification PCBs, which were used in hundreds of commercial applications, such as in electrical, heat transfer, and hydraulic equipment, and as plasticizers in plants, plastics, and rubber products Classification Distribution Distribution DIOXIN AND FURAN INVENTORIES National and Regional Emissions of PCDD/F Distribution PCBs and PBDEs – production volume trends Distribution Distribution Distribution Hazards Hazards Hazards Hazards Hazards Hazards Degradation Degradation Photocatalytic oxidation Degradation Photo Chemical Reaction Lab Degradation Degradation Identification by GC/MS Degradation 1 Principle of Fenton Fe2+ + H2O2 Fe3+ + HO· + HO- k1 58 M-1S-1 Fe3+ + H2O2 Fe2+ + HOO· + H k2 0.02 M-1S-1 HO2. + HO2. O2 + H2O2 K3 8.6×105 M-1S-1 2 Principle of Fenton/UV ? 0.14 ? 313 ? 0.017 ? 360 Degradation 3 Principle of Fenton/Vi The disadvantages of Photo-Fenton: 1 PH 3 2 The low using rate of H2O2 3 The demand of UV Degradation Recently, many researchers have made some improvements about Fenton reagent. 1 Synthesis of new metal organic compound Degradation 2 Loaded catalyst