甲醇水溶液模拟.docVIP

请帮我做一下aspen的混合物的凝固点的模拟。谢谢了！ 1、目的 甲醇水溶液的凝固点比水低。因此。一定比率的甲醇水溶液可以防冻。甲醇质量分数越大，凝固点越低。但是加过多甲醇有时候会造成污染或浪费。我们生产主任是通过把不同比率的溶液放入冰箱中实验。其实网上也能查出结果来。但我想学会用aspen软件算出不同浓度的甲醇水溶液的凝固点。 2、参考 我从网上找了一篇甲醇水溶液的模拟说明。全英文的。介绍整个模拟过程。没有图。 全文如下： ? TFREEZE1.INP ? ? Example of using TFREEZ to estimate freeze points ? ? The ASPEN PLUS TFREEZ property can be used as an estimate of the ? freeze-out temperature for a component in either a liquid or vapor ? mixture. The value of TFREEZ is the temperature where a component ? just begins to freeze-out at a given concentration and pressure. ? Freeze-out temperatures can be determined for vapors such as CO2, or ? for liquids such as water. In this example, the water freeze out ? temperature for water and methanol solutions will be calculated. ? See the TFREEZE2 example for an illustration on predicting ? gas-solid freeze out temperatures. ? ? The freeze-out temperature is determined from fugacity. To ? accurately estimate liquid freezing point depressions, a liquid ? fugacity model such as NRTL or ELECNRTL must be used to estimate the ? decrease in chemical potential due to the presence of other ? components. These components can be molecular or ionic. Methanol ? for example in water solutions or the Na+ and Cl- ions when sodium ? chloride is dissolved in water. The precipitated solid is assumed to ? be a single pure component making the chemical potential of the solid ? constant with respect to the concentration of other components. It ? is also important that the parameters for these models be accurate ? over the temperature range of interest. ? ? The recommended physical property route for solid fugacity (PHIS) is ? PHIS06 which uses the PHS0LIQ model by default. This model ? calculates the solid fugacity from the liquid fugacity and the solid ? heat of fusion. The solid heat of fusion is calculated at a ? reference temperature that is specified in the Prop-Set used to ? declare the TFREEZ property. For liquid systems, the use of the same ? liquid fugaci