陈伟秋论文6月3号解释.doc

摘要 高纯石墨已经成为航空航天、国防和国民经济发展中重要的原材料，现有的石墨提纯方法各有优缺点。一般石墨产品的纯度无法满足高纯石墨行业的要求，因而，高纯石墨材料的开发、生产已成为石墨材料向更宽、更深领域发展亟需解决的问题之一。 本论文通过多次实验，探索出一种采用液相化学法然后用络合剂酒石酸、柠檬酸、三乙醇胺络合石墨中剩余的金属离子，氢氧化钠去除剩余的硅而且用价格低的生石灰处理废液提纯高纯石墨的改进方法。用本方法生产高纯石墨，产品质量稳定可靠，不会造成氟对环境的危害也能有效地降低生产成本。 本研究首先采用碱酸法对细颗粒鳞形石墨进行提纯工艺研究，使其灰分由3．17％提升至0.47％。本文分析了柠檬酸、酒石酸、NaOH、三乙醇胺对石墨纯度的影响，确定其中影响较大的因素，进行正交实验，找出影响程度为：酒石酸量＞NaOH＞三乙醇胺。就实验目前已有的细鳞片石墨经预处理后，提纯石墨确定的最佳工艺条件为：柠檬酸、酒石酸、NaOH、三乙醇胺与石墨的质量比分别为0.008、0.006、0.65、0.006，可得到石墨固定碳含量达到的99.97%。 关键词 高纯石墨 细鳞形石墨 碱酸法 络合剂 Abstract High purity graphite has become aerospace, defense and national economic development of the main raw material, the existing graphite purification methods has its advantages and disadvantages. General graphite product purity can meet the requirement of high purity graphite industry, therefore, high purity graphite materials development, production has become graphite materials wider and deeper areas to develop one of the problem to be solved. This paper, by the experiments, explores a kind of using liquid chemical method and then with complexing agent tartaric acid, citric acid, applying triethanolamine complexation graphite in the rest of the metal ion, sodium hydroxide to remove the remaining silicon with low price and quick lime treatment of wastewater purification high purity graphite improving methods. Use this method production high purity graphite, reliable product quality, wont cause harm to the environment of fluorine can effectively reduce the production cost. This study used first to alkaline acid method to fine solids scale form graphite for purification processes and researches the ash from 3.17% up to 0.47%. This paper analyzes the citric acid, tartaric acid, NaOH, triethanolamine on the influence of the purity graphite, identified the great influence factors that orthogonal experiment, and find out the influence degree for: tartaric acid NaOH triethanolamine . Will the experiment of the existing fine flake graphite after the pretreatment, process to d