固体物理,考试,led,Solid State Physics-7.ppt

§7.4.6 Approximate Solution Near a Zone Boundary We suppose that the Fourier components are small in comparison with the kinetic energy of a free electron at the zone boundary. We first consider a wavevector exactly at the zone boundary at , that is , at Here so that at the zone boundary the kinetic energy of the two component waves are equal. of the potential energy If is an important coefficient in the orbital 29 This result also follows from the discussion of 5 . We retain only those equations in the central equation that contain both coefficients and One equation of 31