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The Synthesis of Carbon Quantum Dots CQDs speaker：叶江林 组员：汪冬冬 叶江林 王长来 章小同 杜娟 高峰 魏绍娟 郭亚丽 潘世友 刘克 潘祺 材料合成化学 2015-1-5 1、Introduction 2、Synthetic approaches 2.1 Arc discharge method 2.2 Chemical ablation 2.3 Electrochemical carbonization 2.4 Laser ablation 2.5 Microwave irradiation 2.6 Hydrothermal/solvothermal 2.7 Template Content 3、Future target 1. Introduction Carbon quantum dots CQDs are a new class of quantum dots materials Advantage: 1 Low toxicity, 2 Biocompatibility, 3 Low cost, 4 Chemical inertness, 5 Fluorescence properties. …… Ref. 1 Youfu Wang, Aiguo Hu. J. Mater. Chem. C, 2014, 2, 6921–6939 2 Shi Ying Lim, Wei Shen and Zhiqiang Gao, Chem. Soc. Rew., 2015, 362-281 Inorganic quantum dots Carbon quantum dots Great potential applications 2. Synthetic methods Many methods have been proposed to prepare CQDs during the last decade, which can be roughly classified into “Top-down” and “Bottom-up” approaches. Ref. Youfu Wang, Aiguo Hu. J. Mater. Chem. C, 2014, 2, 6921–6939 Arc discharge soot introduce carboxyl functional groups suspension CQDs Ref. Xu X Y，Ray R，Gu Y L，et al． J Am Chem Soc，2004，126 40 : 12736-12737. oxidative gel electrophoresis method extraction Arc processing 2.1 Arc discharge method carbonaceous materials carbon source 2.2 Chemical ablation H2SO4 HNO3 Ref. 1 L. Shen, L. Zhang, M. Chen, X. Chen and J. Wang, Carbon,2013,55, 343. 2 H. Peng and J. Travas-Sejdic, Chem. Mater., 2009, 21, 5563 Electrochemical carbonization CQDs solution a degassed acetonitrile solution withTBAP Cycled applied potential Purification process evaporating the acetonitrile from solution dissolving the remaining solid in water dialyzing the aqueous solution with a cellulose ester membrane bag Three electrodes 2.3 Electrochemical Ref: [1] Zheng L, Chi Y, Dong Y, et al. J Am Chem Soc, 2009, 131 13 : 4564-4565.. [2] Wang Y F, Hu A J. J. Mater. Chem. C, 2014, 2, 6921 CQDs Experimental configuration graphite powder cement carbon target Carbon prec
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