矽鋁氧化物對焚化飛灰調質熔渣之水化反應之影響-abstractsonline.docVIP

Effects of SiO2 and Al2O3 on the Hydration Characteristics of MSWI Fly Ash Slag Paper # WM-3h -568 Kae-Long Lin Department of Environmental Engineering, National ILan University, Taiwan 260, ROC Kuen-Sheng Wang, Su-Yuan Chou and Jheng-Ru Shen Graduate Institute of Environmental Engineering, National Central University, Taiwan 320, ROC Nien-Fu Wang Graduate Institute of Civil Engineering, National Central University, Taiwan 320, ROC ABSTRACT Municipal solid waste incinerator fly ash, comprised of mixed cyclone ash and lime-reactant ash, can be characterized as having a high melting point, and is thus difficult to melt effectively and economically, without modification of its components. This study investigates how the modification of the fly ashs basicity will affect the pozzolanic characteristics of the resultant melts. It was modified by adding SiO2, to bring the basicity closer to unity; subsequent additions of Al2O3 on top of the previous modifications were also evaluated. The pozzolanic characteristics of the samples were evaluated at various curing ages. The compressive strength development, degree of hydration and hydration products, as well as the engineering properties of the pastes were examined. All the slag samples produced from the modified fly ash all met the ASTM C989 specifications for blast furnace slag. The results indicate that increasing the amount of aluminum oxide to raise the basicity will enhance the early hydration characteristics. The XRD and DTA analyses indicated that the main hydrated products of the tested samples included calcium hydroxide CH , calcium silicate hydrate C-S-H , and calcium aluminate hydrates C-A-H . The degree of hydration increased with the curing time, but decreased with the blend ratio. The results of this study demonstrate that MSW fly ash can be melted at a lower temperature when its basicity is modified and can produce the desired type of slag, with pozzolanic characteristics close to or outperforming those of