高分子物理期末试卷.docVIP

高分子物理期末考试 名词解释（=20‘） 熵弹性 蠕变 应力松弛 时温等效原理 熔融指数 表观粘度 次级转变 假塑性流体 触变性流体 滞后 应变硬化 银纹 硬度 脆性断裂 粘弹性 能弹性 理想弹性体 Botlzmann原理 填空题、在聚合物的力学松弛现象中，????和????属于静态粘弹性，???和??属于动态粘弹性。 A.蠕变; B.力学损耗; C.滞后; D.应力松弛. 10、下列哪种力学模型可以模拟交联高聚物的蠕变过程 ???。 A. MAXWELL模型 B . Kelvin模型 C. 四元件模型 D. 多元件模型 四、问答题 请作出PS、PMMA的形变温度曲线 2、示意画出聚合物动态粘弹性的温度谱图，说明温度对聚合物内耗大小的影响。 聚丙烯腈只能用溶液纺丝，不能用熔融纺丝，而涤纶树脂可用熔融纺丝。为什么？ 如何提高聚合物的耐热性？ 计算题（2X10=20’） 某交联橡胶试样于298K时，经物理测试得以下数据：试片尺寸=0.2×1×2.8 cm3;试片质量=0.518g;试片被拉伸一倍时的拉力F=9.8N试由以上数据求此橡胶的网链平均分子量. 2、某聚合物的粘弹行为服从Kelvin模型，其中η值服从WLF方程，E值服从橡胶弹性统计理论，该聚合物的玻璃化转变温度为5℃，该温度下粘度为Pa.s有效网链密度为mol/cm试写出30℃，Pa应力作用下聚合物的蠕变方程。 be carried out in time rust and antirust paint twice. While skeleton construction curtain wall fireproof, antisepsis, mine should be simultaneously, all skeletons complete after the required time and concealed work inspection, acceptance of concealed work qualified before the stone plaque installed. Stone in stone before they can use pollution prevention performance, radiation energy, water absorption properties and bending strength of various performance testing protective treatment and six stone two times, and minimize chromatic aberration, chromatic aberration under control mainly in the specification sheet and the stone material control, specification order form should try to distinguish between separate parts orders. Stone cutting must be carried out according to the same part of the same batch, different parts of different facades of stone panels applied when cutting different symbols of letters or Arabic numerals differentiates, in order to facilitate timely and accurately identify different stone when installing special mounting parts. Resolutely put an end to abuse with abuse. In addition to control and the local color, the other in the stone wall construction should be carried out before publishing, model wall dimensions as 84000mmx2000mm, stone size options for 1200mmx400mm