三元微电解-Fenton氧化回用处理石化废水-改.docVIP

三元微电解-Fenton氧化回用处理石化废水试验研究 杨瑞洪，刘亚凯2 （1.扬州工业职业技术学院 化学工程系, 江苏扬州 225127; 2.常州大学 环境与安全工程学院常州213164pH值为4，停留时间为45min，Al：Fe：C质量比1：2：2，废水经微电解处理后，CODCr去除率可达到47.6%；通过单因素试验考察Fenton试剂氧化最优条件，试验得出Fenton试剂氧化单元的最优条件为：H202投加量为0.8mL/L，反应时间为20min，CODCr去除率可达到71.8%；最后，将微电解-Fenton试剂氧化组合工艺应用于石化废水的深度处理流动实验，可使CODCr、SS及浊度得到较好的去除效果，最大去除率分别为66.7%、73.3%、92.9%，都达到了循环冷却水的用水标准。 【关键词】三元微电解；Fenton氧化；正交试验；回用处理；石化废水 Experimental study of Reused Treatment for Petrochemical Wastewater by Ternary Microelectrolysis-Fenton oxidation Yang Ruihong1, Liu Yakai2 （1. Department of Chemical EngineeringYangzhou Polytechnic Institute，Yangzhou 225127，China; 2. Environment and Safety Engineering College, ChangZhou University, Jiangsu Changzhou 213164，China）Abstract:Ternary micro-electrolysis combined with Fenton oxidation process was used for advanced treatment of petrochemical wastewater to reach the cooling water quality standards which after secondary treatment were studied in this article. The best micro-electrolysis operating conditions was investigated by orthogonal test, experimental results showed that the optimum conditions for micro-electrolysis: liquid to solid ratio of 2, pH value of 4, retention time of 45min, Al: Fe: C mass ratio of 1:2 : 2,CODCr removal rate of wastewater can reach 47.6% after micro-electrolysis treatment; The optimal conditions of Fentons reagent oxidation was investigated by single-factor test, optimal conditions was: H202 dosage of 0.8mL/L, reaction time was 20min, the removal rate of CODCr can reach 71.8%;Finally, the microelectrolysis-Fenton reagent oxidation process was combined for advanced treatment of petrochemical wastewater through flow experiments, removal efficiency of CODCr, SS and turbidity was better and the maximum removal rates were 66.7%, 73.3%, 92.9 %,respectively, the efflunt have reached the circulating cooling water standards. Key words:ternary micro-electrolysis;Fenton oxidation;orthogonality experiment;reused treatment;petrochemical wastewater 废水回用是节水减排的重要途径