化学吸收结合生物还原处理烟气中NOx的小试研究.docVIP

（该文已收录于中国环境科学学会大气分会论文集2009.10，南京大学） 化学吸收结合生物还原处理烟气中NOx的小试研究 刘楠,吴成志,刘芸,蔡灵琳,李伟*(浙江大学环境工程研究所, 浙江 杭州, 310027)Evaluation of Chemical absorption-biological reduction integrated process on the removal of NOx from flue gas in lab-scale. Liu Nan, Wu Cheng-zhi, Liu Yun, Cai Ling-Lin, Li Wei* (Institute of Environmental Engineering, Zhejiang University, Hangzhou, 310027, China) 摘要：本研究采用化学吸收结合生物还原的方法处理烟气中NOx。在该过程中，NOx中的主要成分NO与Fe(II)EDTA络合，并由微生物将NO还原为N2。其中烟气中的O2能够迅速氧化吸收NO的活性成分 Fe(II)EDTA为Fe(III)EDTA，而它可被微生物再生为Fe(II)EDTA。在稳态运行条件下，该过程的NO去除率可达90％；直接生物法仅有29％的去除率；单纯的络合吸收法在相同条件下经过5h的运行，吸收液已无法对NO进行有效的吸收。另外，本实验分离出了Fe(II)EDTA-NO还原菌和Fe(III)EDTA还原菌，并分别研究了它们对Fe(II)EDTA-NO或Fe(III)EDTA的还原情况。 关键词：NOX，烟气，吸收，微生物，Fe(II)EDTA 中图分类号X703.5 文献标识码A 文章编号Abstract: A chemical absorption-biological reduction integrated approach is developed to achieve the NOx removal from the flue gas. In this integrated process, NO (the primary component of NOx) is chelated by Fe(II)EDTA and subsequently reduced to N2 by microorganism. Fe(III)EDTA formed via oxidation by oxygen in the flue gas is simultaneously and biologically reduced back to Fe (II)EDTA. During the steady state operation, the integrated approach for the NO removal can be achieved to 90%, in comparison with 29% by the water-based biofilter. Moreover, full breakthrough of NO was observed in the scrubbing process after 5h of operation at the same condition. Additionally, two dedicated bacterial strains (a Fe(II)EDTA-NO reducing bacterium and Fe(III)EDTA reducing one) were isolated and characterized. Fe(III)EDTA and Fe(II)EDTA-NO reduced by these two bacterial strains was also investigated respectively. Keywords: NOx, flue gas, absorption, biological, Fe(II)EDTA 氮氧化物（NOx）的排放会导致一系列的环境问题，如酸雨、臭氧层空洞、光化学烟雾以及温室效应等。因此，NOx的处理对环境的改善起着非常重要的作用。目前应用比较广泛的烟气脱氮技术主要是一些物化方法，如选择性催化还原法（SCR）和吸收法[1]。但成本高和易产生二次污染是这些传统控制方法的主要缺陷。目前，一种新的化学吸收结合生物还原方法得到了一定的研究，这种方法结合了化学和生物方法的优势[2]。在该过程中，Fe(II)EDTA可提高吸收液对NOx的吸收容量，NO在吸收塔中与Fe(II)EDTA络合，进而被微生物还原为N2[3]。为说明该耦合体系的优势，本文对以络合吸收、直接生物还