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- 2016-10-21 发布于广东
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化工原理理论塔数求解示例
示例
苯(A)~(B)二组分体系在下的气~液平衡数据
t() 80.2 79.9 79 78.1 77.2 76 74.6 72.8 70.5 67 61 汽相y2 0.0000 0.0932 0.1961 0.3085 0.4240 0.5480 0.6620 0.7612 0.8545 0.9415 1.0000 液相x2 0.0000 0.0676 0.1403 0.2186 0.3032 0.3949 0.4947 0.6036 0.7231 0.8545 1.0000 由以上数据画气液平衡线
3.1理论板数计算
3.1.1物料衡算
已知进料量F=240kmol/h,进料组成XF=0.4,进料q=0.5
设计要求:XD=0.995,Xw=0.002
衡算方程 :
3.1.2 q线方程
XF=0.4 q=0.5q线方程为:y=-x+0.8
由q线和平衡线交点确定Xe=0.3338,Ye=0.4662
3.1.3 Rmin和R的确定
R=1.6Rmin=1.6*3.9939=6.3903
3.1.4精馏段操作线方程的确定
精馏段操作线方程:
3.1.5精馏段和提馏段气液流量的确定
已知 D=96.19kmol/h R=6.3903
精馏段:L=RD=614.7kmol/h
V=(R+1)D=710.9 kmol/h
提馏段:L’=L+qF=734.7 kmol/h
V’=V-(1-q)F=590.9kmol/h
3.1.6提馏段操作线方程的确定
提馏段操作线方程:
3.1.7图解法求解理论板数如下图:
根据已知数据在autoCAD中画图得出塔板数为47.98。其中精馏段8块,提馏段39.98块。
因蒸馏釜相当于一块理论板,故总理论板数为46.98块,
已知 XD=0.97,Xw=0.11 XF=0.6q线方程:y苯(A)~(B)二组分体系在下的气~液平衡数据
y 0.0000 0.0932 0.1961 0.3085 0.4240 0.5480 0.6620 0.7612 0.8545 0.9415 1.0000 液相x 0.0000 0.0676 0.1403 0.2186 0.3032 0.3949 0.4947 0.6036 0.7231 0.8545 1.0000 2. 画q线方程y=0.6坐标图
画出气液平衡线和q线方程的交点(Xe,Ye)并标注
4.Rmin和R的确定(根据交点Xe,Ye 和XD=0.97
R=1.6Rmin
画出精馏段方程
坐标图(根据求得的R和已知XD=0.97
6.提馏段操作线方程的确定
已知 D=121.86 R=(以求出)
计算:精馏段:L=RD= V=(R+1)D=
提馏段:L’=L V’=V+213.86
(画出该方程图)
最后得出
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