石墨烯变形.pptxVIP

石墨烯/聚合物变形郑冉冉 秦雪 藏冰 刘、快速蒸干溶剂法文献一：Hierarchical Nanohybrids with Porous CNT-Networks Decorated Crumpled Graphene Balls for Supercapacitors石墨烯褶皱微球：ACS Appl. Mater. Interfaces 2014, 6, 9881?9889 褶皱石墨烯微球是GO和Fe3+悬浮液通过超声喷雾器喷洒产生气溶胶液滴，快速蒸干溶剂和物理变形产生。CNT在褶皱石墨烯微球上生长是通过化学蒸汽沉积的方法。ACS Appl. Mater. Interfaces 2014, 6, 9881?9889二、通过GO的自组装，在聚合物微球上包覆GO法。文献二：Graphene-Wrapped Hybrid Spheres of Electrical Conductivity石墨烯片层阴离子，聚合物微球表面带阳离子（乳液聚合），通过离子间作用力自组装成石墨烯包裹聚合物的微球。ACS Appl. Mater. Interfaces 2011, 3, 2904–2911a b(a) Scanning electron microphotographs and (b) transmission electron microphotograph of graphene-wrapped hybrid spheres.ACS Appl. Mater. Interfaces 2011, 3, 2904–2911文献三：An aggregation-mediated assembly of graphene oxide on amine-functionalized poly(glycidyl methacrylate) microspheres for core–shell structures with controlled electrical conductivityJ. Mater. Chem. C,2014, 2, 6462–6466 通过GO的pH响应沉积调节自组装到聚合物微球上。pH越小，GO在聚合物微球上的厚度越大，因为pH高时，在聚合物表面上的GO和未付上的GO没有吸引力,当酸性增大时，GO上的羧基质子化不稳定，GO易沉积微球上；当酸性太强时，沉积速度太快，形成一些GO聚集物。J. Mater. Chem. C,2014, 2, 6462–6466 文献四：Graphene oxide coated core–shell structured polystyrene microsph -eres and their electrorheological characteristics under applied electric ?eld先在乙醇中分别超声分散，再混合搅拌。核壳结构的PS-GO微球是通过PS与GO间的π-π共轭作用。J. Mater. Chem, 2011, 21, 6916–6921Directing Silicon?Graphene Self-Assembly as a Core/Shell Anode for High-Performance Lithium-Ion BatteriesLangmuir,2013, 29, 744?749石墨烯包覆硅纳米线，使作为电极材料，提高其放电性和导电性等。制备：石墨烯包覆硅纳米线，通过GO与硅纳米线自组装APTES:其他方法：超声乳化-蒸发溶剂法，密度梯度和溶液过程法，碱金属剥离石墨烯法，冰冻模板化pH调节自组装法。文献五：Graphene Oxide Nanosheet Wrapped White-Emissive Conjugated Polymer Nanoparticles(a) Schematic illustration of the preparation of GO-PFO NPs. SEM image of GO-PFONPs. GO是两亲性的物质，能留在在水油界面起到表面起活性剂的作用。 通过超声乳化，蒸发溶剂。ACSNANO,2012,8(5),4248-4256文献六：Inclusion and exclusion of self-assembled molecules inside graphene scrolls and control of their inner-tube diameter石墨烯卷轴通过密度梯度和溶液过程合成。空心石墨烯卷是通过溶液溶解或者加热使LCAs分解产生。LCAs满足两亲性，能自组装，含有氨基