406聚四氟乙烯超细纤维负载二氧化钛光催化性能.docxVIP

第 44 卷第 1 期硅酸盐学报Vol. 44，No. 12 0 1 6 年 1 月JOURNAL OF THE CHINESE CERAMIC SOCIETYJanuary，2016DOI：10.14062/j.issn.0454-5648.2016.01.14聚四氟乙烯超细纤维负载二氧化钛光催化性能陶丽琴，赵义侠，康卫民，程博闻，乔春梅(天津工业大学，省部共建分离膜与膜过程国家重点实验室，天津 300387)摘 要：以静电纺聚四氟乙烯(PTFE)超细纤维为载体，采用浸渍–烧结法制备出 PTFE 超细纤维负载二氧化钛(TiO2)催化膜。 研究了该催化膜在紫外光下，不同反应条件对亚甲基蓝的光催化降解性能影响，探讨了负载型 TiO2 光催化剂的循环回收利用 率。结果表明：通过浸渍–烧结法可以成功制备出 PTFE 超细纤维负载 TiO2 光催化膜，经 450 ℃煅烧后 TiO2 为锐钛矿晶型； 在波长为 365 nm，功率为 300 W 的紫光灯照射 55 min，浸渍负载 5 h 制备的 TiO2/PTFE 超细纤维催化膜对初始浓度为 5 mg/L、 体积 100 mL 的亚甲基蓝溶液催化降解除率可达 99%；在经过 5 次循环后，催化剂对亚甲基蓝的降解率仍达 46%，回收利用 率较高。关键词：聚四氟乙烯超细纤维；二氧化钛；电纺；光催化中图分类号：TQ134.1+1文献标志码：A文章编号：0454–5648(2016)01–0089–06网络出版时间：2015-12-23 05:19:59网络出版地址：/kcms/detail/11.2310.TQ1719.014.htmlPreparation of Titanium Dioxide Loaded on Polytetrafluoroethylene Superfine-fiber and Its Photocatalytic PerformanceTAO Liqin, ZHAO Yixia, KANG Weimin, CHENG Bowen, QIAO Chunmei(State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin 300387, China)Abstract: Polytetrafluoroethylene (PTFE) nanofibers were prepared by an electrostatic spinning technology. Titanium dioxide (TiO2) particles were loaded on the PTFE nanofibers via dipping and sintering. The morphology and structure of the photocatalyst film were characterized. Effects of reacting conditions of the TiO2/PTFE superfine-fiber film on the photocatalytic degradation of methylene blue under UV–Vis light irradiation were investigated. In addition, the recycling utilization of load type TiO2 light catalyst was also discussed. The result show that the TiO2(as anatase)/PTFE nanofiber photocatalyst film was obtained after calcination at 450 ℃. Under the violet light (300 W, 365 nm) irradiation, when irradiation distance is 30 cm and after irradiation for 55 min, the TiO2/PTFE superfine-fiber film is prepared by dipping for 5 h. Its degradation rate for methylene blue with initial concentration of 5 mg/L and volume of 100 mL is 99%. The degradation efficiency of methylene blue is still 46% after recycli