有机反应机理第2章-2摘要.pptVIP

根据表中的数据，表中所列Diels-Alder反应是 否为协同机理？ 表中的数据显示，对于前两个反应，活化体积 ?V?的值比反应的体积变化?V0值更负， 说明过渡态的结构比产物更紧凑，为什么？ 4.1. Calculate the activation parameters (?H? ?S?) at 80oC from the date given for the reaction shown below and explain the results of your calculation. 习题4 4.2. The hydrolysis of benzoyl chloride was studied in the mixtures of water and acetone with different water content at 25oC. In all cases the reaction was first order with respect to benzoyl chloride. Calculate the activation entropies for the reaction in each mixture from the date of rate constants and a