毕业设计(论文)－无机高分子混凝剂—聚硅酸铝铁(PSAF).docVIP

摘　　要 本文在总结国内外聚硅酸类混凝剂的研究与发展的基础上，以水玻璃、硫酸铝、硫酸铁为原料，制备无机高分子混凝剂—聚硅酸铝铁(简称PSAF)，并对该混凝剂的混凝除浊效能及对印染废水的脱色效能进行了研究和讨论，从而为聚硅酸类混凝剂的工业化生产和工程应用奠定了基础。 本文在酸性条件下制备聚硅酸，优化了聚硅酸的制备工艺条件，系统研究了硅酸的聚合反应过程中pH值、二氧化硅浓度、温度等因素对聚硅酸聚合过程中的影响。采用自制的聚硅酸制备聚硅酸铝铁混凝剂。研究(Al+Fe)/Si摩尔比、Al/Fe摩尔比、搅拌时间、投加量等因素对模拟悬浊水样的除浊效能的影响。 实验结果表明：聚硅酸铝铁混凝剂具有优良的混凝除浊效能；在适宜的条件下，对活性染料模拟水样、分散染料模拟水样均有较好的脱色效果，对活性染料模拟水样的脱色率最高可达88.48%，对分散染料模拟水样的脱色率最高可达80.84%，与硫酸铝、三氯化铁、聚硅酸铝、聚硅酸铁相比，聚硅酸铝铁有较好的混凝除浊脱色效能。  Abstract The researches related to the development of metal-polysilicate complex coaulant were reviewed.The polysilicate aluminum ferric(PSAF)was prpared by using water glass, aluminium sulphate,ferric chloride as raw materials;the viscosity as controlling parameter. Coagulation property was analyzed and discussed systematically on the turbidity removal and the decorization of dyeing wastewater containing reactive red and disperse brilliant blue dyes,which could provide the basis for PSAF’s industrial production and engineering application development of being used actually. Polymerized silicic acid was prepared under acidic conditions.The processes for the praparation of polymerized silicic acid were optimized,and the viscosity was used as the key indicator of polymerization degree of polymerized silicic acid.The influences of temperature,pH value,SiO2 concentration,and different acidifiers on the viscosity were systematically investigated. PSAF with high efficiency was prapared by using self-made polymerized silicic acid,and the processes of PSAF were optimized.The(Al+Fe)/Si mole ratio,Al/Fe mole ratio,the viscosity of polymerized silicic acid,aging time,dosage,pH value on turbidity removal and dye decorization were studied. The result showed that:PSAF had excellent coagulation property on the turbidity removal;for the synthetic reactive red and disperse brilliant blue dye wastewater,the use of PSAF could achieve 88.48%and 80.48%of dye removal efficiency in appropriate conditions,respectively.PSAF were evaluated with comparation of different