ZAS系論文钐掺杂透明ZnO-Al_2O_3-SiO_2系微晶玻璃的制备及表征.docVIP

ZAS系论文：钐掺杂透明ZnO-Al_2O_3-SiO_2系微晶玻璃的制备及表征 【中文摘要】微晶玻璃是一种微晶体和玻璃相均匀分布的新型无机非金属材料,广泛的应用于机械力学、光学、电子与微电子、生物医学和化学化工材料等领域。本文采用熔融-晶化法制备了Sm3+掺杂ZnO-A1203-SiO2系微晶玻璃,在基质玻璃组成不变的情况下,研究了不同晶核剂Tio2、ZrO2和P205对Sm3+掺杂ZnO-A12O3一SiO2系微晶玻璃析晶性能及光谱性质的影响。通过差示扫描量热分析(DSC),制定出玻璃的晶化热处理制度；通过X射线衍射(XRD),观察不同热处理条件下,晶相的变化,并确定其晶相为Zn2SiO4和ZnAl2O4；通过扫描电子显微镜(SEM),观察微晶玻璃的结构与形貌,并利用比例尺估算出晶粒平均尺寸大约在10-30nm;通过紫外-可见-近红外分光光度计(UV-Vis-NIR),测定微晶玻璃的光透过率,随着热处理温度的升高和热处理理时间的增加,透过率会有降低趋势,其在近红外区域光透过率最高可达90%;通过荧光光谱研究了Sm3+在ZnO-Al2O3-SiO2系微晶玻璃中的光学性质,Sm3+在微晶玻璃中比在基质玻璃中的发光性能强,并且热处理条件不同,荧光光谱中发射峰的强度也不同。 【英文摘要】The glass-ceramic is a kind of inorganic nonmetal materials that contain the uniform distribution of micro crystal and glass phase. It is widely used in mechanical, optics, electronics and microelectronics, biological medicine and chemical materials etc. The Sm3+ ion doped ZnO-Al2O3-SiO2 system glass-ceramics were prepared by melting and crystallization.When the base glass composition is changeless, The crystallization and optical properties of the Sm3+ ion doped ZnO-Al2O3-SiO2 system glass-ceramics were studied by doping the different nucleation agent TiO2, ZrO2 and P2O5. The heat treatment system of crystallization is draw up by Differential Scanning Calorimetry (DSC); The crystalling phase in different heat condition is observed by X-ray diffraction (XRD), and the crystalling phases of the ZnO-Al2O3-SiO2 system glass-ceramics are Zn2SiO4 and Zn1Al2O4; The structure and morphology of glass-ceramics are observed by scanning electron microscopy (SEM), and the average grain size estimated by the measuring scale is about 10～30nm, The optical transmittances of the base glass and glass-ceramic are measured by UV-Vis-NIR spectrophotometer. with the rise of temperature and time of heat treatment, The optical transmittance will have a trend to decrease. Its highest optical transmittance can reach 90% in the near infrared area; The optical properties of Sm3+ ion in the ZnO