2009学年度高二化学有机化学基础测试试题苏教版选修5.docVIP

2009学年度高二化学有机化学基础测试试题选修5 考试时间：90分钟 满分：100分 可能用到的相对原子质量：H：1 C：12 N：14 O：16 第I卷（选择题，共48分） 一、选择题（共分，每题2分，每小题均只有一个选项符合题意） 1．·······························································································（ ） A B．乙醇脱水 C．石油裂解 D．煤炭干馏 2．······································································（ ） 3．······················（ ） 4．下列用水就能鉴别的一组物质是 ······························································································（ ） A．苯、己烷、四氯化碳 B．苯、乙醇、四氯化碳 C．硝基苯、乙醇、四氯化碳 D．溴苯、乙醇、乙酸 5．1999年比利时发生奶粉受二噁英污染事件。二噁英是一类芳香族化合物的多氯代衍生物的总称，结构稳定，难以被自然分解，是公认的最危险的致癌物质之一，2,3,7,8-四氯二苯并二噁英是其中的一种，结构如图：下列说法中不正确的是 ·································（ ） A．它的分子式为C12H4O2Cl4 B．它不能发生加成反应 C．它的一溴取代物有一种 D．此分子中共平面的原子最多有22个 6．·······（ ） 7．下列反应不需要水浴加热的是 ································································································（ ） A．苯与溴的取代反应 B．苯的硝化反应C．酚醛树脂的制备 D．乙醛的银镜反应 8．乙醇、苯酚、乙酸中，含有共同的基团是 ··········································································· （ ） A．羧基 B．醛基 C．羟基 D．羰基 9．能发生银镜反应，但滴入石蕊试液后不变色，若加入少NaOH溶液并滴入酚酞试液共煮，则红色消失。这种有机物是 ·············································································································（ ） A．甲酸 B．乙酸 C．甲酸甲酯 D．乙醛 10．在乙酸乙酯、乙醇、乙酸水溶液共存的化学平衡体系中加入重水（D2O），经过足够长的时间后，可以发现，除水外体系中含重氢的化合物是······································································（ ） A．只有乙醇 B．只有乙酸 C．只有乙酸乙酯、乙醇 D．乙醇、乙酸 11．某烯烃（只含一个碳碳双键）与氢气加成后的产物是：则该烯烃的结构式可能有几种·································································（ ） A．1 B．2 C．3 D．4 12． A、B两种有机物不论以何种比例混合，只要混合物总质量不变，完全燃烧时生成H2O的量也不变。则A、B的组合不可能是··································································································（ ） A．C10H8和C6H8O3 B．C2H2和C6H6 C．C2H4和C3H6 D．CH4和C2H4 13．体育竞技中服用兴奋剂既有失公平，也败坏了体育道德。某种兴奋剂的结构简式如图所示。有关该物