NMR基础知识介绍.pptVIP

* For a single carbon spin or a few spins, we can still unravel the coupling patterns, however when a lot of chemically different carbon atoms are present in the sample, the scalar coupling of the carbon with the proton spins give rise to a very complicated spectrum. * When the proton spin is up, the carbon resonates at w+J/2. After the proton p-pulse, the carbon resonates at w-J/2. If we apply a series of p-pulses at the proton resonance, and if we do this fast compared to the size of the J-coupling, the carbon will resonate at the average of the frequencies (w-J/2) and (w+J/2), which is w. T