综述化学镀镍.doc

Role of electroless nickel diffusion barrier on the combinatorialplating characteristics of dense Pd/Ni/PSS composite membranesMurali Pujari, Amrita Agarwal, Ramgopal Uppaluri 化学镀镍扩散阻挡层的致密钯/镍/PSS复合膜的复合镀层作用特点 （作者）Pujari, Amrita Agarwal, Ramgopal Uppaluri article info 文章信息. Keywords: Electroless plating Sonication Surfactant Pd composite membrane Interdiffusion 关键词：化学镀 超声 表面活性剂 钯复合膜 互扩散 Abstract ： This work addresses the combinatorial plating characteristics of dense Pd/Ni/porous stainless steel (PSS)composite membranes in comparison with Pd/PSS membranes. While Pd/PSS membranes were fabricated using 0.1 m nominal pore size PSS supports, Pd/Ni/PSS membranes were fabricated using 0.5 and 0.1 m nominal pore size PSS supports. Both Ni and Pd films were deposited using an identified novel electroless plating process that characterizes the optimal utilization of surfactant, sonication and reducing agent contacting pattern in Pd electroless plating baths. It was observed that the combinatorial plating characteristics for Pd/Ni/PSS membranes were significantly different and poorer in comparison with those obtained for the Pd/PSS membranes. In summary, it has been inferred that the introduction of nickel interdiffusion barrier was not fruitful to reduce the critical thickness of dense Pd film without jeopardizing upon the pore densification. 摘要： 摘要：这个实验解决了用Pd / PSS膜比较致密的Pd/镍/多孔不锈钢（PSS）复合膜的组合电镀特点。而钯/ PSS膜用0.1M标称孔径的PSS支持制造，钯/镍/ PSS膜进行使用0.5m和0.1m制备米标称孔径的PSS支持。两者Ni和Pd膜使用鉴定新颖的化学镀工艺表征的表面活性剂，超声处理的最佳利用和还原剂在钯电镀浴接触图案沉积。据观察，对于钯/镍/ PSS薄膜的组合电镀特征是显著不同，与含量少那些钯/ PSS薄膜获得比较。总之，已经推断，在引入镍互相扩散阻挡并不很有成效减少致密Pd膜的临界厚度，而不经孔隙致密化损害。 Introduction： 介绍： In comparison with pure palladium foils, palladium composite membranes possess superior combinations of hydrogen permeability, separation factor, mechanical strength and cost [1,2]. Typically,palladium composite membranes refer to a thin dense Pd filmdeposited on a macro porous support such as alumina or sintered stainless steel or in conel [3,4]. Am