配位化学2b-分子轨道导论.pptVIP

Td E 8C3 3C2 6S4 6σd A1 A2 E T1 T2 1 1 1 1 1 1 1 1 -1 -1 2 -1 2 0 0 3 0 -1 1 -1 3 0 -1 -1 1 (Rx,Ry, Rz) (x, y, z) X2 +y2 +z2 (2z2-x2-y2, X2-y2) (xy,xz,yz) Oh E 8C36C2 6C4 3C2(=C42) i 6S4 8S6 3σh 6σd A1g A2g Eg T1g T2g A1u A2u Eu T1u T2u 1 1 1 1 1 1 1 1 1 1 1 1 –1 –1 1 1 -1 1 1 -1 2 –1 0 0 2 2 0 -1 2 0 3 0 -1 1 -1 3 1 0 -1