薄膜材料Ch02.pptVIP

Zhiming YU, Dept. of MSE, CSU Zhiming YU, Dept. of MSE * Surf. Sci. Thin Solid Films * Chapter 2 Thermodynamics of the Surface 1. Surface free energy (SFE) 3. Curvature surfaces Man points: 2. Anisotropy of the SFE of Crystal Gibbs, Josiah Willard, On The Equilibrium of Heterogeneous Substances(1875-1878), in The scientific papers of J. Willard Gibbs, Vol. 1,(Longmans, London and Dover, New York, 1901), p. 315. “ We may regard ? as expressing the work in forming a unit of the surface of discontinuity, but it cannot properly be regarded as expressing the tension of the surf