吡嗪-2,3-二羧酸镍配位聚合物的水热合成技术报告.doc

摘要 金属-有机配位聚合物(Metal-organic coordination polymers, MOCPs)，又被称作金属-有机框架(Metal-organic frameworks, MOFs)，它是由有机配体和金属离子通过自组装形成的具有周期性网络结构的金属-有机骨架晶体材料，具有丰富的空间拓扑结构和独特的磁学、电学和光学等性质，具备巨大的研究价值与前景。近几年，设计与合成金属-有机配位聚合物已成为晶体工程、材料化学、配位化学、超分子化学等领域的研究重点。 本论文主要研究在水热体系下，以来自金属盐·的Ni2+离子为配位中心，以吡嗪-2,3-二羧酸()、3,5-吡啶二甲酸()、为主配体，4,4-联吡啶()、邻菲罗啉(1,10-phenanthroline)、4,5-咪唑二甲酸(4,5-Imidazole dicarboxylic acid) 为辅助配体，以水作为溶剂，经大量实验成功合成了一例吡嗪-2,3-二羧酸镍配位聚合物Ni(H20)2（C6H2N2O4)，并且研究了金属离子、溶剂、配体、浓度、反应温度和时间等因素对配位聚合物晶体结构的影响。本实验还通过单晶X-射线衍射分析对所合成的配位聚合物进行了结构表征分析，得出该配位聚合物属于正交晶系，Pcca空间群，金属离子中心采取八面体构型进行配位，热重分析表明该化合物具有良好的热稳定性。 关键词：Ni金属-有机配位聚合物，水热合成，合成条件，晶体结构 Abstract Metal - organic coordination polymers (MOCPs), also known as Metal - organic frameworks,(MOFs), it is made of Metal ions and organic ligands with periodic network structure formed through self-assembly of Metal - organic skeleton crystal materials, has the rich spatial topological structure and unique magnetic, electrical and optical properties, such as great research value. In recent years, the design synthesis of metal - organic coordination polymers has become a crystal engineering, materials chemistry, coordination chemistry, research focus in the field of supramolecular chemistry, etc. Under the hot water system, this thesis mainly research in metal salt Ni（NO3)2·6H2O, Ni2 + ions for coordination center, 2, 3 - Pyrazinedicarboxylic acid, 3, 5 - Pyridinedicarboxylic acid, L2 (4, 4 - oxidiphthalic acid) as the main ligand, 4, 4 - Bipyridine, adjacent phenanthroline (1, 10 phenanthroline) and 4,5-Imidazole dicarboxylic acid as the auxiliary ligand, water as solvent, through a large number of successful synthesis of a case of pyrazine, 2, 3 coordination polymer C6 dicarboxylic acid nickel H6 Ni N2 O6, and metal ions are studied, solvents, ligands, concentration, reaction temperature and time on the influence of coordination polymer cry