第4章1H-核磁共振.pptVIP

谱图解析与结构确定步骤 ? =1+10+1/2(-12)=5 δ 2.1单峰三个氢，—CH3峰结构中有氧原子， 可能具有： δ 3.0和δ 4.30三重峰和三重峰为基团 O—CH2CH2—相互偶合峰 正确结构： δ 7.3芳环上5个氢，单取代 δ3.0 δ4.30 δ2.1 * #3, p88 1Tesla=10,000 Gauss * #1（赵瑶兴），p122. * #3(n),p154(#5) * #1，p122(图3-10）。 图中表明，乙醇在不同浓度时，羟基峰强度随浓度的降低氢键减弱， ?值向高场移动。 * * * #3(n), p232(图5.10). Chemical nonequivalence complicates the spectrum (slightly differenct ?, HA=2.75 and HB=3.09 ppm ). HA and HB are chemically and magnetically nonequivalent. Because HA and HB are nonequivalent, and because HC is coupled differently to HA than to HB (3JAC ? 3JBC), the n+1 Rule fails. #3