06络合滴定法-14化工-20150505汇编.pptVIP

* * * * * * * * * * 20’ * 20’ 逐级稳定常数 Ki ● ● ● ● ● ● ● ● ● K 表示相邻络合物之间的关系 M + L = ML ML + L = ML2 MLn-1 + L = MLn 累积稳定常数 ? ? 表示络合物与配体之间的关系 [ML] [M][L] K1= [ML2] [ML][L] K2= [MLn] [MLn-1][L] Kn= [ML] [M][L] ?1=K1= [ML2] [M][L]2 ?2=K1K2= [MLn] [M][L]n ?n=K1K2 ···Kn= 逐级稳定常数K与累积稳定常数β 二. 溶液中各级络合物的分布 [ML] = ? 1 [M] [L] [ML2] = ? 2 [M] [L]2 ● ● ● [MLn ]= ? n [M] [L]n ● ● ● M + L = ML ML + L = ML2 MLn-1 + L = MLn cM=[M]+[ML]+[ML2]+…+[MLn] =[M](1+ ? 1 [L]+ ? 2 [L]2+…+ ? n [L]n) 分布分数 δM=[M]/cM = 1/(1+?1[L]+?2[L]2+…+?n[L]n) δML=[ML]/cM = ?1[L]/(1+?1[L]+?2[L]2+…+?n[L]n)