《基于分子运动理论的煤吸附规律研究》.docVIP

基于分子运动理论的煤吸附规律研究* 张天军1 许鸿杰1 任树鑫1 李树刚2 (1.西安科技大学 理学院，陕西 西安 710054；2.西安科技大学 能源学院，陕西 西安 710054) 摘要：为了研究煤的吸附规律，在理想气体模型下，根据分子运动理论、速度反应理论进行推导并对煤体表面能进行计算，得出了Langmuir吸附常数a、b与温度T及表面自由能Ed的关系式；从三个不同矿井采集煤样，采用WY-98B吸附常数测定仪在不同温度下对煤样进行了吸附甲烷的实验，获得了Langmuir吸附常数a、b随温度T变化的关系曲线；通过对理论结果与实验结果相比较的方法，验证了从分子运动理论出发所得结论的合理性，提供了分子运动理论在研究煤吸附性能上的应用方法；给出了Langmuir吸附系数a、b与吸附温度T的关系式，同时也给出了吸附平衡时的压力Pt与温度T及表面自由能Ed的关系式，这些关系式可以为研究煤的吸附性能提供理论依据。 关键词：朗格缪尔吸附常数 ；速度反应理论；分子运动理论；表面能 中图分类号：TD 712 文献标识码：A Study on the Adsorption Law of Coal Based on the Kinetic Molecular Theory ZHANG Tian-jun1, XU Hong-jie1 ,　REN Shu-Xin 1,　LI Shu-gang2 （1. College of Sciences,Xian University of Science and Technology; Xian 710054,China； 　2. College of Energy Science Engineering,Xian University of Science and Technology; Xian 710054,China） Abstract: Theoretically, under the ideal gas model, the relationships among the Langmuir adsorption constants a and b, temperature T, and free surface energy Ed are obtained by deduction and calculation of surface energy of coal body, based on the kinetic molecular theory and the reaction rate theory. Experimentally, coal samples are gathered from three different coal mines, the WY-98B adsorption constant determinator is used to do the tests of adsorption of methane on coal for the samples under different temperatures, and the relationship curves of Langmuir constants a and b, and temperature T are obtained. By comparing the theoretical results and the experimental results, it is found that the conclusions obtained using the kinetic molecular theory are reasonable. Ways of studying the adsorption performance of coal using the kinetic molecular theory are provided. The relationship between Langmuir constants a and b and adsorption temperature T is given. And the relationship among the Pressure Pt, temperature T, and free surface energy Ed at adsorption equilibrium is also given. These relationships could serve as theoretical bases for the study of adsorption performance of coal. Key