《微波场中铁矿球团煤基直接还原机理研究》.doc

铁精矿氧化球团微波加热煤基直接还原机理研究 黄柱成1，胡兵1， 姜涛1， 彭虎2 （1.中南大学 资源加工与生物工程学院，湖南 长沙，410083； 长沙隆泰微波热工有限公司，长沙 410013） 摘要：为了深入了解铁矿球团在微波场中的升温机制和煤基直接还原行为，本文采用铁精矿氧化球团在外配煤粉的条件下放入微波炉中进行了一系列的非等温还原实验，重点考查了还原物料在微波场中的损耗机理和升温情况，以及球团升温还原过程中的物相和结构性能变化。研究表明，铁矿氧化球团在微波加热煤基直接还原过程中物相和结构的变化可以引起电磁性能的改变，在微波辐射和热应力共同作用下，初始阶段球团中的大颗粒出现碎裂，增加了气体扩散的通道，为球团的快速还原提供了条件；高温和微波辐射下，浮士体和金属铁颗粒很容易出现迁移、聚集和长大，一旦还原气氛不能匹配浮士体的还原速度，浮士体将以氧化亚铁相不断长大,反而不利于球团的深度还原。 关键词：铁精矿氧化球团;直接还原;微波加热;损耗机理 Mechanism research of coal-based direct reduction on iron concentrate oxidized pellets by microwave heating HUANG Zhu-cheng1, HU Bing1, JIANG Tao1, PENG Hu2 （1. School of Mineral Processing and Bioengineering, Central South University, Changsha 410083, China; Changsha SYNO-THERM Co. , Ltd. Changsha 410013 , China ) Abstract: For gaining further insight into the mechanism of temperature rising and coal-based direct reduction of iron concentrate oxidized pellets on microwave field, a series of nonisothermal reduction experiment were done in laboratory microwave oven through mixed iron concentrate oxidized pellets and anthracites, this paper mainly studied the loss mechanism and temperature rising behavior of reduction materials on microwave field, and the change of ferrum phases and structural performance in the process of heating and reduction. The research shows that the electromagnetic properties of materials will change as the change of ferrum phases and structural performance, in the beginning stage of microwave heating, particles appears fragmentation under the both of microwave electromagnetic field and thermal stress, it is help to the rapid reduction of iron oxides; the particles of Wustite and metal iron are very easily to remove and aggregation and growing up in the condition of high temperate and microwave radiation, so that the wustite will transform into oxide ferrous and growing up rapidly, it makes the direct reduction of pellets more difficult. Key words: Iron concentrate oxidized pellet; direct reduction; microwave heating; loss