ZnO纳米制备及其修饰电极在重金属离子检测中的应用论述.doc

ZnO纳米材料制备及其修饰电极在重金属离子检测中的应用 ZnO纳米材料制备及其修饰电极在重金属离子检测中的应用 摘要： 本文介绍了ZnO纳米材料制备及其修饰电极在重金属离子检测中的应用。以醋酸锌与氢氧化钠,氨水反应生成ZnO。然后将ZnO溶液滴到金电极表面上，再沉积Au制成ZnO/Au修饰电极，利用此修饰电极作为工作电极，采用三电极体系，对水溶液中Cu2+进行电化学检测。检测的实验结果表明，纳米ZnO/Au修饰电极能很好的检测出溶液中Cu2+含量，最低检测线为4×10-10mol/L,在8×10-10mol/L到1×10-5mol/L浓度范围内，方波伏安法峰高和浓度成良好的线性关系，线性相关系数为0.983。因此灵敏度高，利用该电极重复测量11次，结果表明峰高强度随实验次数变化不大，变化幅度在4%之内，这说明重复性较好，电极稳定性很好，准确度极高。由实验结果我们可知该电极对污水中Cu2+含量的检测很有用处。 关键词：纳米、氧化锌、修饰电极、电化学检测、Cu2+。 Abstract: This paper introduces the ZnO nanometer material preparation and application of modified electrode in the detection of heavy metal ions. With zinc acetate and sodium hydroxide, ammonia reaction ZnO. Then the ZnO solution to the gold electrode surface, and deposition of Au into ZnO/Au modified electrode, the modified electrode as working electrode, the three electrode system, electrochemical detection of Cu2+ in aqueous solution. Detection results show that, ZnO/Au nanoparticles modified electrode can detect Cu2+ content in solution is very good, the lowest detection line is 4 × 10-10mol/L,8× 10-10mol/L to 1 × 10-5mol/L concentration range, a good linear relationship between the square wave voltammetry peak height and concentration, the linear correlation coefficient of 0.983. Therefore, high sensitivity, 11 times of repeated measurement of the electrode, the results showed little change in peak intensity increases with the number of experiments, the change in the rate of 4%, indicating that the electrode has good stability, high accuracy, good repeatability. From the experimental results we show that this electrode on Cu2+ content in the effluent exceed the standard test no useful. Keywords: nanometer, zinc oxide, modified electrode, electrochemical detection, Cu2+. 1、引言 纳米材料纳米级结构材料简称， 氧化锌是一种的白色的颜料，俗名叫锌白。，在加热时，由白浅黄逐步变为柠檬黄色，当冷却后柠檬黄色便退去，利用这一特性，把它加入温度计或掺入油漆中，做成变色温度计或变色油漆因ZnO有收敛性和杀菌能力，在医药上常调制成软膏使用，ZnO还可用作催化剂 氧化锌常被用于生产婴儿爽身粉等产品，是一种无毒的无机物，人体不会对其产生排异反应，因而安全性高。此外，氧化锌纳米粒子的体积小，具有不妨碍细胞活动的优点 纳米氧化锌是一种新型无机功能料，其粒径介于1~100nm之间。由于颗粒尺寸，