高等有机化学-第六章不饱和碳碳键的加成反应精品.pptVIP

The stereochemistry of the Diels–Alder reaction * * decylMe3 NMnO4 and Me3SiBr * 6-26 The Sakurai Reaction 6-27 Conjugate Addition of Boranes to Activated Double Bonds 6-28 Radical Addition to Activated Double Bonds 6-29 Radical Addition to Unactivated Double Bond 6-30 Radical Cyclization 6-32 Acylation of Activated Double Bonds and of Triple Bonds 6-33 Addition of Alcohols, Amines, Carboxylic Esters, Aldehydes, and so on. 6-34 Addition of Aldehydes Rhodiumcompounds or YbOTf3 6-35 Hydrocarboxylation 100–350oC and 500–1000 atm 6-36 Carbonylation, Alkoxycarbonylation and Aminocarbonylation of D