《有机波谱分析》习题答案..docVIP

有机波谱分析习题参考答案 “有机质谱”部分习题参考答案 A C2H3Cl, B C2H6S 2. C2H2Cl2 , ClCH=CHCl 3. m/z 142 M?43 (?C3H7), m/z 142 C9H20N, (n-C4H9)3N, 4． 略 5．（a）CH3COCH2CH2CH2CH3, or CH3COCH2CH(CH3)2 CH3COCH(CH3)CH2CH3 (c) CH3COC (CH3)3 6. (a) CH3CH2CH2COOCH3, (b) (CH3)3CCOOH (c) CH3CH2COOCH2CH3 7. p-CH3COC6H4NO2 8. m/z 172, M?28 (C2H4) , C6H5OBr , BrC6H4OCH2CH3 C6H5COOCH2CH2CH2CH3 , m/z 123 M?55，酯的双氢重排。 “核磁共振氢谱”部分习题参考答案 CH3CH2COOCH3 , 2.CH3CH2OCOCH(NO2)CH3 (a) C6H5CH(CH3)OCOCH3 , (b)C6H5CH2CH2OCOCH3, (c) p-CH3C6H4COOCH2CH3 4. HOCH2CH2CN , 5. CH3CH2OCOCH2N(CH3)2