均匀实验设计在Bi2WO6合成中的应用.docVIP

均匀实验设计在Bi2W6合成中的应用In the past preparation of powder Bi2WO6, often using the traditional solid state reaction method.The method simple equipment and easy to operate, but mixture of solid particles only the overall homogeneity without local uniformity can not be done as the two kinds of fluids may reach the full mix. Disadvantage of this approach are: (1) Raw material mixing the various components is difficult; (2) The entire process easy to mix impurities, difficult to obtain high-purity powder; (3) Reaction process often requires higher temperatures ( 700 ℃); (4) Non-uniform powder particle size, surface activity is poor so easy to form a family reunion, resulting in lower photocatalytic activity. In recent years, there are some new ways of preparation Bi2WO6 powders reported in the literature, such as the hydrothermal method, microwave solvothermal method and the melting of the slow cooling process, and so on. Generally speaking, the choice of preparation conditions must be cheap and easy to find raw materials, simple process, good performance, taking into account operation of non-toxic, environmental sanitation, low-cost and other issues. In this paper, use Bi (NO3) 3 ? 5H2O and Na2WO4 ? 2H2O as raw materials to make Bi2WO6 powder. Using the uniform experimental design, by adjusting the precursor pH, reaction temperature, raw material ratio and reaction time these four factors. With the action of EDTA on the powder samples Bi2WO6. As the pH values from 2.5 to 11.5, Bi2WO6 spatial structure will gradually change. Keywords: Uniform Experimental Design，Nano, Bi2WO6, Hydrothermal Method, Photocatalytic Signature of Supercisor: 第一章 文献综述 1.1引言 光催化技术作为治理环境问题的一种方法，是目前最活跃的研究领域之一，寻找高效率的光催化剂是该领域的首要任务。以TiO2为代表的氧化物半导体材料是最经典，也是研究最多的光催化剂。然而，氧化物半导体的禁带宽度通常都比较大。例如，锐钛矿型TiO2的禁带宽度为3.12eV，只有在波长小于387nm的紫外线下才能激发其催化活性。在到达地面的太阳能中，这一波段的能量尚不足5％，而可见光部分的比例却占到太阳能的45％左右。因此，开发可见光响应的光催化剂非常重要。硫化物的禁带宽度通常比氧化物窄，具有优于氧化物的可见光催化活性。例如，硫化镉的禁带宽度为2.4eV，比TiO2的禁带宽度窄，其光响应范围比TiO2宽，因而能实