水泥窑协同处置生活垃圾焚烧飞灰过程中的二噁英迁移和降解.docxVIP

水泥窑协同处置生活垃圾焚烧飞灰过程中的二噁英迁移和降解特性研究摘要：为了解生活垃圾焚烧飞灰中的二噁英在水泥脱氯预处理过程中的迁移特性以及在水泥窑内的热降解特性，依托北京市琉璃河水泥有限公司的生活垃圾焚烧飞灰水泥窑协同处置示范线，开展了生活垃圾焚烧飞灰的水洗脱氯预处理和水洗后飞灰向水泥窑投加的工程试验研究。结果表明：烘干烟气中和水泥窑窑尾烟气中二噁英排放浓度低于《水泥窑协同处置固体废物污染控制标准》（GB 30485—2013）中所规定的标准限值0.1 ng I-TEQ/Nm3，结晶氯盐中二噁英含量仅为2.8ng I-TEQ/kg；以每小时进入水洗罐的原飞灰中所含二噁英量为100%计，经过水洗处理后，99.97%的二噁英仍留在脱氯飞灰中，仅0.081%和0.14%的二噁英分别通过烘干废气和结晶盐排出；以每小时投入水泥窑窑尾烟室的飞灰所含二噁英为100%计，仅0.82%、0.13%和0.0021%的二噁英分别随窑灰、熟料、烟气排出，飞灰中的二噁英在水泥窑内的消减率达到了99%以上，实现了较为彻底的降解。关键词：水泥窑，协同处置，二噁英，生活垃圾焚烧飞灰，水洗预处理中图分类号：X705 文章编号：文献标志码：ADOI：Study on the migration and degradation characteristics of dioxin during the process of cement kiln co-processing municipal solid waste incineration fly ashAbstract: In order to understand the dioxin migration characteristics during the water-washing pretreatment process and thermal degradation characteristics during the co-processing process in the cement kiln, based on the demonstration line of cement kiln co-processing municipal solid waste incineration (MSWI) fly ash in Beijing Liulihe Cement Co. Ltd., an industrial test about MSWI fly ash dechlorination by water-washing pretreatment and washed fly ash feeding into the cement kiln was carried out. The results show that the dioxin emission concentrations in the flue gases of fly ash drying machine and cement kiln inlet were lower than the emission limit value of 0.1 ng I-TEQ/Nm3 prescribed in《Standard for pollution control on co-processing of solid wastes in cement kiln》 (GB 30485—2013), and the dioxin concentration in the crystallized chlorine salt was only 2.8ng I-TEQ/kg; Taking the mass of dioxin in the raw fly ash fed into the washing tank in 1h as 100%, after water-washing pretreatment, 99.97% of dioxin remained in the dechlorinated fly ash, only 0.081% and 0.14% of dioxin was discharged in the fly ash drying machine flue gas and the crystallized chlorine salt, respectively; Taking the mass of dioxin in the fly ash fed into the cement kiln in 1h as 100%, only 0.82%, 0.13% and 0.0021% of dioxin was dischar