核磁共振解析2.pptVIP

2D NMR 图谱 Direct H-C correlations (HSQC)Interaction between H and C atoms through one bond. 1H-1H correlations (COSY) Proton interaction trough three bonds. Long-range 13C-1H correlations (HMBC).Interaction between 13С and 1Н nuclei trough two and three bonds. Nuclear Overhauser Effect (NOE) Interaction between 1H-1 and 1H-2 when they are distanced in the space by r 5 ?. NOE produced NOESY / ROESY 2D NMR spectra. * 结构鉴定: 化合物2-1 H-21a H-21b H-4 H-3 Me-23 Me-20 1H NMR of 2-1 H-2 C-1 C-22 C-9 C-10 C-4 C-21 C-3 C-19 C-20 13C NMR of 2-1 C-2 H-4 H-3 H-2 Me-20 H-18 H-15 H-14 H-13a H-16a H-17a