芳腈基聚合物的微结构控制与耐高温介质材料研究.ppt

* 聚芳醚腈晶体微观形貌 DSC curves and XRD patterns of the crystalline PEN-Ph sheet and amorphous PEN sheet 3.单一组分复合聚芳醚腈介电材料 SEM images of (a)crystalline PEN sheet; (b)amorphous PEN sheet Polarizing microscope images of crystalline PEN * 3.单一组分复合聚芳醚腈介电材料 The plots of dielectric property versus frequency for (a) and (c) PEN-Ph before crosslinked; (b) and (d) crosslinked PEN-Ph single-component composite films. (e) (f) The influence of crystalline and crosslink on dielectric properties(e) and breakdown strength(f). 单一组分复合材料介电性能 * Conventional One-step method 3.单一组分复合聚芳醚腈介电材料 静电纺丝法制备单一组分复合材料 * 4.填充型聚芳醚腈复合介电材料 Designed zero, one, and two dimensional fillers for advanced composites. 特殊结构的填料 Ref. Applied Physics Letters, 2013, 102(10): 102903. Ref. Journal of Materials Chemistry A, 2016, 4(15): 5592-5604. Ref. Accounts of Chemical Research, 2012, 45(8): 1356-1364. * 以化学为手段、通过分子设计构建不同形貌、不同形状的高介电填料实现对微结构的控制。 4.填充型聚芳醚腈复合介电材料 * 以化学为手段、通过分子设计构建不同形貌、不同形状的高介电填料实现对微结构的控制。 4.填充型聚芳醚腈复合介电材料 * 4.填充型聚芳醚腈复合介电材料 Lichtenecker’s mixture law Bruggeman formula BaTiO3/PEN复合介电薄膜 The pictures of PEN and BT/PEN composites films The dielectric property of PEN and BT/PEN composites films as function of mass fraction of BT * 4.填充型聚芳醚腈复合介电材料 CPEN-g-BT /PEN复合介电薄膜 The schematic diagram of preparation of CPEN-g-BT The TEM images of CPEN-g-BT TGA curves of CPEN-g-BT * 13 4.3 CPEN-g-BT /PEN复合介电薄膜 增长了200% 4.填充型聚芳醚腈复合介电材料 The SEM images of CPEN-g-BT/PEN composites with 5% and 40% CPEN-g-BT Dielectric property of CPEN-g-BT/PEN composites * 4.填充聚芳醚腈复合介电材料 刺状TiO2-MWCNTs/PEN复合介电薄膜 TiO2-MWCNTs及TiO2-MWCNTs/PEN复合材料制备 Schematic diagram of preparation of TiO2-MWCNTs and TiO2-MWCNTs/PEN composites SEM and TEM images of MWCNTs and TiO2-MWCNTs * 刺状TiO2-MWCNTs/PEN复合介电薄膜 4.填充聚芳醚腈复合介电材料 TiO2-MWCNTs/PEN复合薄膜流变特性 (a) Storage modulus (G), (b) loss modulus (G), (c) complex viscosity (η*) and (d) tan (delta) of the TiO2-MWCNT/PEN composite films as a function frequency. SEM images of fractured cross-section of TiO2-MWCNT/PEN com