11章_化学动力学基础(一)方案.ppt

The rates of chemical reactions The variation with time of the concentration of a reactant in a second-order reaction. The grey line is the corresponding decay in a first-order reaction with the same initial rate. For this illustration, klarge = 3ksmall. The rates of chemical reactions The rates of chemical reactions The approach of concentrations to their equilibrium values as predicted by eqn 19 for a reaction A 3/4 B that is first-order in each direction, and for which k = 2k. The rates of chemical reactions The relaxation to the new equilibrium composition when a reaction initially at eq