氢化酶 2课件.pptVIP

Group Meeting 2010. 08. 15 Chem. Commun., 2010, DOI: 10.1039/c0cc00724b Directing protonation in [FeFe] hydrogenase active site models by modifications in their second coordination sphere Salah Ezzaher , Adolf Gogoll , Clemens Bruhn and Sascha Ott* 2010, 46, 5775-5777 Subtle changes in the second coordination sphere of Cl2bdtFe2(CO)4(Ph2P–CH2–X–CH2–PPh2)] (bdt = benzene-1,2-dithiolate, X = NCH3, NCH2CF3, CH2) that do not influence the electronic character of the Fe2 center can however direct protonation to three different sites: the N in the bis-phosphane, the Fe–Fe b