过渡金属氧化物刘俊明.pptVIP

LSSMS, PLD-Lab. PLD Lab, / LSSMS, PLD Lab. J. –M. Liu (刘俊明)Email: liujm@ Group page / 4d/5d oxides: T=Ru as an example from GC, MPLB (2008) Simplified phase diagram for (Ca,Sr)n+1RunO3n+1 Rich phases competing to each other, depending on n G. Cao et al. MPLB22, 19 (2008) 4d/5d oxides: T=Ru as an example Very different behaviors between Sr- Ca-based systems 4d/5d oxides: phenomena possible physics in n=2 Crystal fields Hund’s rule interactions p-d electron hybridization Electron-lattice coupling Spin-orbital coupling (~0.4 eV (5d), 0.1 eV (4d), 0.02 eV (3d)) A set of balances between dif