2016溶液热力学习题.pptVIP

4-19 将1.55 g磷及1.27 g碘溶于100 gCS2中，计算沸点升高多少?(已知磷及碘在CS2中分别以P4，I2形式存在，二者的Mr分别为123.88及254.0，CS2的kb=2.40 K．kg．mol -1 。) 解： 则 ?Tb = kb·b(P4 + I2) = 2.40 K·kg·mol-1×0.175 mol·kg -1 = 0.42 K Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. ?Tf = kf·bC = 40 K·kg·mol-1×5.85×10-3mol·kg-1 = 0.234 K (2) ?Tf = kf·bB = 40 K·kg·mol-1×0.2506 mol·kg-1 = 10.0