有机反应机理第1章-1课件.ppt

When a nucleophile attacks the exocyclic C atom of the nonaromatic compound fulvene, the electrons from the C=C p bond go to the endocyclic C and make the ring aromatic 习题1 1.1 Draw as many reasonable resonance structures for each of the following compounds as you can 1.2 Explain each of the following observations Amides (R2NCOR) are much more nucleophilic on O than they are on N (b) Compound 1 has a much larger dipole moment than its isomer 2. 共振结构稳定性的判别 与判别Lewis结构稳定性的原则相同 ① B, C, N, O等满足八隅体规则的共振结构更稳定 ② 电中性共振结构较电荷分离的共振结构稳定 ③ 电负性原子带负电荷，电正性原子带正电荷较稳定 缺电子原子与带未共享电子对的原子相邻时的共振 哪一共振结构更稳定？ 右