ChCH. 13 Molecular Structure.ppt

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2016-12-30 发布于上海
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ChCH. 13 Molecular Structure.ppt

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C. Johannesson II. Molecular Geometry(p. 183 – 187) Ch. 6 – Molecular Structure A. VSEPR Theory Valence Shell Electron Pair Repulsion Theory Electron pairs orient themselves in order to minimize repulsive forces. A. VSEPR Theory Types of e- Pairs Bonding pairs - form bonds Lone pairs - nonbonding e- A. VSEPR Theory Lone pairs reduce the bond angle between atoms. B. Determining Molecular Shape Draw the Lewis Diagram. Tally up e- pairs on central atom. double/triple bonds = ONE pair Shape is determined by the # of bonding pairs and lone pairs. C. Common Molecular Shapes 2 total 2 bond 0 lone C. Common Molecular Shapes 3 total 3 bond 0 lone C. Common Molecular Shapes 3 total 2 bond 1 lone C. Common Molecular Shapes 4 total 4 bond 0 lone C. Common Molecular Shapes 4 total 3 bond 1 lone C. Common Molecular Shapes 4 total 2 bond 2 lone C. Common Molecular Shapes 5 total 5 bond 0 lone C. Common Molecular Shapes 6 total 6 bond 0 lone D. Examples PF3 D. Examples CO2 * * I II III Lone pairs repel more strongly than bonding pairs!!! Bond Angle Know the 8 common shapes their bond angles! LINEAR 180° BeH2 TRIGONAL PLANAR 120° BF3 BENT 120° SO2 TETRAHEDRAL 109.5° CH4 TRIGONAL PYRAMIDAL 107° NH3 BENT 104.5° H2O TRIGONAL BIPYRAMIDAL 120°/90° PCl5 OCTAHEDRAL 90° SF6 4 total 3 bond 1 lone TRIGONAL PYRAMIDAL 107° F P F F *