可放大、绿色的烯丙位C-H键电化学氧化.docxVIP

可放大、绿色的烯丙位C-H键电化学氧化/nature/journal/v533/n7601/abs/nature17431.htmlEvan J. Horn, /nature/journal/v533/n7601/abs/nature17431.htmlBrandon R. Rosen, /nature/journal/v533/n7601/abs/nature17431.htmlYong Chen, /nature/journal/v533/n7601/abs/nature17431.htmlJiaze Tang, /nature/journal/v533/n7601/abs/nature17431.htmlKe Chen, /nature/journal/v533/n7601/abs/nature17431.htmlMartin D. Eastgate /nature/journal/v533/n7601/abs/nature17431.htmlPhil S. Baran. Scalable and sustainable electrochemical allylic C–H oxidation. Nature, 2016(533):77–81.烯丙醇和烯丙酮衍生物在合成中是很重要、多功能的一类中间体。烯丙醇可发生Sharpless反应，或衍生化后进行Cope重排、clais