煤层气发电高温NOx烟气SCR处理技术及应用探讨..doc

煤层气发电高温NOx烟气SCR处理技术及应用探讨 　　孙宇1*，张增胜1，冉献强1，潘荣幸1，范建伟1,2 　　(1. 上海同济科蓝环保设备工程有限公司;2. 同济大学环境科学与工程学院) 　　摘要：煤层气作为一种资源，越来越受到政府和企业的重视。其中，煤层气发电是煤层气利用的重要途径之一。但煤层气发电排放的高温尾气中含有NOx，会对环境造成污染，且随着氮氧化物对人类活动及环境影响的日趋严重，国家对煤层气发电高温烟气中NOx的排放标准要求会越来越严格，相应的法规政策也将随之出台。煤层气发电烟气由于其高温特性(约500°C)，燃煤电厂脱硝常用的V2O5/TiO2系列蜂窝式催化剂并不适用于煤层气发电脱硝，选择高温催化剂对尾气进行处理是综合考虑各个因素的首选方法。应用GJ-HC-5型催化剂的SCR处理技术可以在较宽的温度范围内(400～600°C)对烟气中的NOx的去除率始终保持在90%以上，是一种可行的煤层气发电高温烟气的脱硝方法。 　　关键词：煤层气发电;高温烟气; 氮氧化物(NOx); SCR;催化剂 　　Discussion on SCR treatment technology and application of the high temperature NOx exhaust gas from coal bed methane power plant 　　Yu Sun1, Zengsheng Zhang1, Xianqiang Ran1, Rongxing Pan1, Fan Jianwei1,2 　　(1. Shanghai Tongji Clearon Environmental Protection Equipment Engineering Co., Ltd.; 2. College of Environmental Science and Engineering, Tongji University) 　　Abstract: As a resource, coal bed methane (CBM) has been given more and more attention of the government and enterprises. Among them, the CBM power plant is one of the most important ways of CBM utilization. But the emissions of exhaust gas from CBM power plant which containing NOx can cause pollution to the environment. As nitrogen oxides have become increasingly serious, environmental impacts of human activities and state of CBM power plant of NOx in high temperature exhaust gas emission standard will be more and more strictly. As to the corresponding laws, regulations and policies will be introduced. Because of its high temperature properties (about 500°C) of CBM power plant exhaust gas, the V2O5/TiO2 cellular catalyst which commonly suitable for coal-fired power plant denitration can’t apply to CBM power plant denitration. High temperature catalyst of exhaust gas treatment is the preferred method of considering various factors. Application of GJ-HC-5 catalyst for SCR treatment technology which be in relatively wide temperature range (400～600°C), the removals of NOx in exhaust gas had stayed above 90%. So it is a feasible CBM power plant of high temper