荧光探针的发展和应用荧光探针的发展和应用.doc

Supplementary materials for: Perylene diimide based “turn-on” fluorescence sensor for detection of Pd2+ in mixed aqueous media Hai-xia Wang a, b,(, Yue-he Lang a, Hui-xuan Wang a, Jing-jing Lou a, Hai-ming Guo a, b, Xi-you Li c,( a School of Chemistry and Chemical Engineering, Key Laboratory of Green Chemical Media and Reactions of Ministry of Education, Henan Normal University, Xinxiang 453007, China b School of Environmental Science, Henan Normal University, Xinxiang 453007, China email: hxwang5270@163.com (H. Wang) c School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China email: xiyouli@ (X. Li) Contents Page S1: Title of the paper, authors along with the contents. Page S2-S4: Copy of the 1H and 13C NMR spectra of PDI-1, PDI-2 and PDI-3. Page S5: Photophysical properties of PDI-1, PDI-2 and PDI-3 derivatives in different solvents at room temperature; Fluorescence spectra change of PDI-2 and PDI-3 upon addition of different metal(8.0 equiv) ions; UV-vis spectra of PDI-1 (6.0 μM) in the presence of different metal ions (8.0 equiv). Page S6: Job’s plots in DMF/H2O (v/v, 7/1) and acetonitrile; Fluorescence spectra changes of PDI-1 (5.0 μM) in the presence of Pd2+in acetonitrile and chloroform; ESI mass spectra of PDI-1 in the presence of 1.0 equiv PdCl2 in CH3CN. Page S7: Job’s plots of PDI-1 (5.0 μM) in the presence of Pd2+in chloroform; Influence of pH on fluorescence intensity of PDI-1 (5.0 μM) in the absence and presence of 1.0 eq Pd2+; Benesi-Hildebrand analysis results. Fig. S1 1H NMR (400 MHz) spectrum of PDI-1 in CDCl3. Fig. S2 13C NMR (100MHz) spectrum of PDI-1 in CDCl3. Fig. S3 1H NMR (400 MHz) spectrum of PDI-2 in CDCl3. Fig. S4 13C NMR (100 MHz) spectrum of PDI-2 in CDCl3. Fig. S5 1H NMR (400 MHz) spectrum of PDI-3 in CDCl3. Fig. S6 13C NMR (100 MHz) spectrum of PDI-3 in CDCl3. Table S1: Photophysical properties of PDI-1, PDI-2 and PDI-3 derivatives in different solvents at room temperature Fig. S7 Fl