低温氧漂稿1..docVIP

两种低温氧漂剂在棉织物漂白中的应用 田斌1, 汪南方1, 翦育林1, 陈建军2 (1 湖南工程学院化学化工学院，生态纺织材料及染整新技术湖南省高校重点实验室，湖南湘潭，411104 2 益阳龙源纺织有限公司，湖南益阳，413002） 摘要：针对传统棉织物漂白工艺中能耗高、纤维损伤大等问题，比较研究了二种低温氧漂剂SQA和LTB-01在漂白过程中温度、低温氧漂剂浓度、H2O2浓度、Na2CO3的浓度对织物性能的影响。采用单因素试验方法确定了两类低温氧漂剂漂白优化工艺为：80℃×60min，精练酶2.1g/L，低温氧漂剂0.5g/L， H2O2 (30%) 11g/L，Na2CO3 1.0g/L。该工艺在保证棉织物白度的前提下，降低了能耗，纤维的损伤降低。 关键词：低温氧漂；活化剂；白度，强力 Two low temperature oxygen bleaching activators for bleaching cotton fabrics Bing Tian1, Nanfang Wang1, Yulin Jian1, Jianjun Chen2 (1 School of Chemistry chemical Engineering, Hunan Institue of Engeering, Key Laboratory of Ecological Textile Materials Novel Dyeing and Finishing Technology, Hunan Provincial Education Department, XiangTan 411101 2 Yiyang Longyuan Textile Co. Ltd., Yiyang 413002 ) Abstract：With concerns of high energy consumption, fiber damage and other issues in the traditional hydrogen peroxide bleaching process of cotton fabric, two low temperature oxygen bleaching activators (SQA and LTB-01) were adopted for bleaching cotton fabrics at low temperature. Effects of temperature, activator, H2O2, and Na2CO3 concentrations on the properties including whiteness, capillary effect, and strength were investigated. By using the single factor experiment method, it is found that the optimal bleaching process for the two low temperature oxygen bleaching activators is 80℃ for 60min, scouring enzyme 2.1 g/L, bleaching activator 0.5 g/L, 30% H2O2 11g/L, Na2CO3 1.0 g/L. This low temperature process could significantly reduces the energy consumption and fiber damage with the same whiteness and capillary effect to those of the traditional high temperature process. Key words: Low temperature bleach; Bleaching activator; Whiteness; Strength 双氧水由于对环境友好、处理织物白度高、不泛黄等优点，被大量应用于纺织染整行业中漂白织物，但传统工艺的高温条件使得加工过程能耗高、纤维损伤大等，因此研究具有高效低温的双氧水活化剂/催化剂，对减少废水排放、提高纺织品的质量具有很重要的现实意义。近年来，国内外研究者相继开放了一系列氧漂活化剂/催化剂，其中一部分产品已应用于洗涤行业，但成功应用于染整中的报道尚未出现(看了你的参考文献，报道应该很多了，请加上相关的文献报道，并简要地作论述）。其中低温漂白活化剂的漂白机理：活化剂+双氧水→过氧酸，过氧酸是一种氧化性强于双氧水的氧化剂，可在较低温度