蒽、蒽油及多环芳烃检测方法进展.docVIP

蒽、蒽油及多环芳烃检测方法进展 李锡东*，丁华，殷丽娜，周建峰，朱佳丽 (江阴出入境检验检疫局，江苏，江阴，214443 ) 摘要: 本文对蒽、蒽油及多环芳烃在标准中采用的方法和其它检测技术作一综述。简要介绍了化学滴定法测定工业蒽中的蒽含量、超临界流动色谱法测定柴油机燃料和航空燃料中的多环芳烃、核磁共振氢谱法(1HNMR)测定硫化橡胶中的多环芳烃检测标准。多环芳烃的其它检测技术介绍了薄层色谱、电化学、分光光度法(紫外、荧光、磷光)、热透镜光度法、表面增强拉曼光谱、免疫学测定、纳米孔技术、毛细管电泳、毛细管电色谱、分子印迹技术、飞行时间质谱检测技术。 关键词: 蒽；蒽油；多环芳烃；检测技术 中图分类号： O625.15 文献标志码： 文章编号： Detection Methods Progress of Anthracene , Anthracene oil and Polycyclic Aromatic hydrocarbons Li Xi-dong*, Ding hua,Yin Li-na,Zhou Jian-feng,Zhu Jia-li (Jiangyin Entry-exit Inspection And Quarantine Bureau,Jiangsu,Jiangyin,214443 ) Abstract: Methods used in the standards and other detection technologies of anthracene,anthracene oil and polycyclic aromatic hydrocarbons were reviewed.Testing standards of anthracene content in technical anthracene with chemical titration, polycyclic aromatic hydrocarbons content in diesel fuels and aviation turbine fuels with supercritical fluid chromatography, polycyclic aromatic hydrocarbons content in vulcanized rubber compound with proton nuclear magnetic resonance spectroscopy(1HNMR)were briefly introduced.Other technologies for detecting polycyclic aromatic hydrocarbons: thin layer chromatography,electrochemical,spectrophotometry(Uv,fluorescence, phosphorescence),thermal lens spectrophotometry,surface-enhanced raman spectroscopy,immunoassay,nanopore technology,capillary electrophoresis,capillary electrochromatography,molecular imprinting technology,time-of-flight mass spectrometry were introduced． Key words: Anthracene;Anthracene oil;Polycyclic aromatic hydrocarbons;Detection technologies 蒽，俗称“绿油脑”，为多环芳烃，主要由蒽油类物质中分离得到，常用作发光材料、制造蒽醌和染料、杀菌剂等。蒽油类物质中的主要成分也为多环芳烃（PAHs），主要为蒽、荧蒽、菲、芴、苊、芘、咔唑等[1]的混合物。PAHs有萘、苊烯、苊、芴、菲、蒽、荧蒽、芘、苯并[a] 蒽、? 、苯并[b] 荧蒽、苯并[k] 荧蒽、苯并[a] 芘、茚并[1,2,3 -cd] 芘、二苯并[a,h] 蒽、苯并[g,h,i]苝等[2]。蒽、蒽油类物质被REACH法规列为高关注度物质（SVHC）[3]。PAHs有强致畸性、致癌性和致突变性，已成为世界各国共同关注的有机污染物,PAHs的积累已经越来越严重地威胁着人类的健康。本文就蒽、蒽油及多环芳烃