污水處理生物絮体絮凝沉淀机理分析的综述.docxVIP

第37卷第1期2009年1月同济大学学报(自然科学版)J0URNAL OF mNGJI UNIVERSIrrY(NA ⅢRAL SCIENCE)Vo1．37 No．1Jan．2009文章编号：0253—374X(2009)01—0078—06污水处理生物絮体絮凝沉淀机理分析的综述周琪，林涛，谢丽，谭学军(同济大学环境科学与T程学院，上海200092)摘要：通过介绍胞外聚合物(EPS)架桥、DLVO理论和疏水作用力3种最具代表性的理论体系，阐述了生物絮体絮凝沉淀过程、影响因素以及有待解决的问题．分析结果表明：生物絮体分泌的EPS所含蛋白质含量越少，其絮体沉淀效果越好；而疏水作用力却随EPS中蛋白质增加而加强，疏水作用力较大生物絮体絮凝能力较好，疏水作用力同时受到表面电荷的影响．此外，DLV0理论解决了EPS架桥无法解释的抗絮凝反应问题，离子强度在一定范围内越大，则絮体絮凝能力越好．关键词：活性污泥；絮凝沉淀性能；胞外聚合物；DLVO理论；疏水作用力中图分类号：X 829 文献标识码：AReview of Mechanism of BionocculatiOn andSettleability of Activated Sludge BioflocsgHOU ，LIN Tao，XIELi，TANXuejun(School of Environmental Science and Engineering，Tongji Unversity，Shanghai 200092，China)Abstract：Bioflocculation of activated sludge iS crucial tooverall performance and eficiency of the treatment process aswell as the settleability．The bindings between flocs are dueto the intermolecular interactions， which can be mainlycategorized into 3 interdependent and interactional typesincluding bridging of extracellular polymeric substance(EPS)，DLVO-type interactions and hydrophobic interactions．Flocs and EPS carry negative charges and zeta potentials thatnot only produce the electrostatic interactions but createbridges among cells by means of divalent and trivalentcations．EPS contains more protein and carbehydrate than anyother substances，the IOW concentration of which iS believedto correlate with good settleability but poorly hydrophobicinteractions． Moreover。low hydrophobicity which iS alsoaffected by surface charge， is associated with poorflocculation． Also high ionic strength contributes to goodperformance of bioflocculation．The goal of this study is togain a comprehensive insight into sludge floc characteristicsand to identify the key factors which determine the solid-liquidseparation prope rties of activated sludge．Key words： activated sludge flocs； biOn0cculatiOn；settleability；EPS；DLVO；hydrophobicity活性污泥法是废水处理领域运用最为广泛的方法之一．在活性污泥系统中，污泥的生物絮体絮凝沉淀能力是决定系统处理效果的关键因素．活性污泥的絮凝沉淀能力与生物絮体密切相关．深入研究生物絮体的形成机理及影响因素对提高系统处理效率有十分重要的意义．活性