本科学位论文-发展烟气同时脱硫脱硝技术.docVIP

摘 要 随着我国的工业化步伐加快，大气污染也相应加重。研究表明，燃烧过程排放的二氧化碳是引起温室效应的主要物质，所排放的S02、NO以及飞灰颗粒又是造成大气污染的主要来源。如何消除这些污染是一个亟待解决的问题。 本文基于湿法脱硫占据国内脱硫市场主导地位的基本国情，开展了与湿法脱硫相结合的湿法协同脱硫脱硝技术研究，采用硫酸亚铁、氨水和铵根离子/添加剂多元溶剂同时脱硫脱硝，针对氨/硫铵溶液湿法同时脱硫脱硝工艺在工业应用中存在脱硝效率不高的问题，考察了不同操作条件下湿法同时脱硫脱硝特性，并对反应后浆液中的离子浓度和pH值进行了分析与研究。 通过检测同时脱硫脱硝反应浆液中的SO42-、NO3-、NH4+、Fe2+等离子的含量，计算出相应反应物的转化率以及脱硫脱硝效率，为湿法同步脱硫脱硝工艺的优化设计提供了理论依据。其中，浆液中阴离子常用的测定方法为离子色谱法，阳离子常用的测定方法有滴定法、分光光度计法。 实验结果表明:脱硫脱硝浆液中离子的含量随浆液pH值的改变而发生变化。随着浆液pH值的降低，挥发氨的含量迅速减小，氨氮的含量增加，某些稳定阴离子如SO42-的含量无明显变化。 关键词： 湿法； 脱硫脱硝； 离子色谱； 分光光度计； pH值 Abstract With the accelerated pace of Chinas industrialization, air pollution also increased. The results showed that Carbon dioxide was the main substance causing the greenhouse in the combustion process, and the emission of SO2, NOx and fly ash particles was the major source of air pollution. How to eliminate these pollution was a serious problem. Based on the basic conditions that Wet FGD desulfurization market have occupied the leading position at home, this paper carried out the research of simultaneous desulfurization and denitrification. Using ferrous sulfate,multiple solvent of ammonia and ammonium ion/additive for simultaneous desulfurization and denitrification, As the processes of ammonia and ammonium sulfate solution for simultaneous desulfurization and denitrification exist low denitrification efficiency in industrial applications, we investigated the characteristic of simultaneous desulfurization and denitrification under different operating conditions, analyzed and studied the reactive ion concentration and pH of the slurry. By detecting the simultaneous desulfurization and denitrification reaction slurry content of SO42-, NO3-, NH4 +,Fe2 + and other ions, we can calculate the conversion rate of the reactants and the corresponding desulfurization and denitrification efficiency, a theoretical basis for optimized design of the wet simultaneous desulfurization and denitrification can be provided. The common measuring